Information card for entry 4342610

Structure parameters

• Formula: C26 H70 F6 N4 O6 S2 Si8 U2
• Calculated formula: C26 H70 F6 N4 O6 S2 Si8 U2
• SMILES: C[Si](C)(C)N1[U]23(N([Si](C)(C)C)[Si](C)(C)C)[O]=S(O[U](C[Si]1(C)C)(N([Si](C2)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[O]=S(O3)(=O)C(F)(F)F)(=O)C(F)(F)F
• Title of publication: U(III)-CN versus U(IV)-NC Coordination in Tris(silylamide) Complexes.
• Authors of publication: Hervé, Alexandre; Bouzidi, Yamina; Berthet, Jean-Claude; Belkhiri, Lotfi; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 5
• Pages of publication: 2474
• a: 11.2771 ± 0.0006 Å
• b: 11.4316 ± 0.0005 Å
• c: 11.6871 ± 0.0007 Å
• α: 80.495 ± 0.003°
• β: 88.841 ± 0.002°
• γ: 62.631 ± 0.003°
• Cell volume: 1316.96 ± 0.13 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0418
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0642
• Weighted residual factors for all reflections included in the refinement: 0.0666
• Goodness-of-fit parameter for all reflections included in the refinement: 0.984
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No