Information card for entry 4346107

Structure parameters

• Formula: C26 H58 N O2 P2 Rh S2 Si2
• Calculated formula: C26 H58 N O2 P2 Rh S2 Si2
• SMILES: [Rh]12(SC(=NC(=[S]2)O[Si](C)(C)C)O[Si](C)(C)C)[P](C(C)(C)C)(C(C)(C)C)CC[P]1(C(C)(C)C)C(C)(C)C
• Title of publication: Chalcogen extrusion from heteroallenes and carbon monoxide by a three-coordinate rh(i) disilylamide.
• Authors of publication: Whited, Matthew T.; Qiu, Lisa; Kosanovich, Alex J.; Janzen, Daron E.
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 7
• Pages of publication: 3670 - 3679
• a: 12.893 ± 0.003 Å
• b: 21.409 ± 0.005 Å
• c: 27.026 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7460 ± 3 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173.15 K
• Number of distinct elements: 8
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1568
• Residual factor for significantly intense reflections: 0.1042
• Weighted residual factors for significantly intense reflections: 0.222
• Weighted residual factors for all reflections included in the refinement: 0.242
• Goodness-of-fit parameter for all reflections included in the refinement: 1.133
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No