Information card for entry 4346108

Structure parameters

• Formula: C50 H90 N4 P4 Rh2
• Calculated formula: C50 H90 N4 P4 Rh2
• SMILES: [Rh]12([P](CC[P]1(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C)N(C#[N][Rh]1([N]#CN2c2ccccc2)[P](CC[P]1(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C)c1ccccc1
• Title of publication: Chalcogen extrusion from heteroallenes and carbon monoxide by a three-coordinate rh(i) disilylamide.
• Authors of publication: Whited, Matthew T.; Qiu, Lisa; Kosanovich, Alex J.; Janzen, Daron E.
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 7
• Pages of publication: 3670 - 3679
• a: 28.2036 ± 0.0017 Å
• b: 11.405 ± 0.0007 Å
• c: 33.691 ± 0.002 Å
• α: 90°
• β: 93.663 ± 0.004°
• γ: 90°
• Cell volume: 10815 ± 1.1 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.06
• Residual factor for significantly intense reflections: 0.0439
• Weighted residual factors for significantly intense reflections: 0.093
• Weighted residual factors for all reflections included in the refinement: 0.1002
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No