Information card for entry 4515752

Structure parameters

• Chemical name: N-(2,6-dimethoxy-phenyl)-2-di-(3,5-ditrifluoromethylphenyl)- phosphinylchlorogold(i)-pyridinium hexafluoroantimonate dichloromethane
• Formula: C31.5 H24 Au Cl6 F18 N O2 P Sb
• Calculated formula: C31.5 H24 Au Cl6 F18 N O2 P Sb
• Title of publication: N-Arylpyridiniophosphines: Synthesis, Structure, and Applications in Au(I) Catalysis
• Authors of publication: Tinnermann, Hendrik; Nicholls, Leo D. M.; Johannsen, Tim; Wille, Christian; Golz, Christopher; Goddard, Richard; Alcarazo, Manuel
• Journal of publication: ACS Catalysis
• Year of publication: 2018
• Journal volume: 8
• Journal issue: 11
• Pages of publication: 10457
• a: 8.9106 ± 0.0012 Å
• b: 12.9646 ± 0.0017 Å
• c: 19.744 ± 0.003 Å
• α: 73.397 ± 0.002°
• β: 82.399 ± 0.002°
• γ: 85.849 ± 0.002°
• Cell volume: 2165.1 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0584
• Residual factor for significantly intense reflections: 0.054
• Weighted residual factors for significantly intense reflections: 0.1243
• Weighted residual factors for all reflections included in the refinement: 0.1264
• Goodness-of-fit parameter for all reflections included in the refinement: 1.114
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Mo-Kα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No