Information card for entry 7000591

Structure parameters

• Formula: C25 H35 Rh
• Calculated formula: C25 H35 Rh
• SMILES: [Rh]123456([c]78cccc[c]48[cH]3[cH]2[cH]17)([CH]1=[CH]5CCCCCC1)[CH]1=[CH]6CCCCCC1
• Title of publication: Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration
• Authors of publication: Garon, Christian N.; McIsaac, Daniel I.; Vogels, Christopher M.; Decken, Andreas; Williams, Ian D.; Kleeberg, Christian; Marder, Todd B.; Westcott, Stephen A.
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 9
• Pages of publication: 1624 - 1631
• a: 7.3306 ± 0.0006 Å
• b: 13.462 ± 0.0012 Å
• c: 20.7134 ± 0.0019 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2044.1 ± 0.3 ų
• Cell temperature: 173 ± 1 K
• Ambient diffraction temperature: 173 ± 1 K
• Number of distinct elements: 3
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0211
• Residual factor for significantly intense reflections: 0.0195
• Weighted residual factors for significantly intense reflections: 0.0488
• Weighted residual factors for all reflections included in the refinement: 0.0497
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No