Information card for entry 7000592

Structure parameters

• Formula: C37 H33 P2 Rh
• Calculated formula: C37 H33 P2 Rh
• SMILES: [Rh]1234([P](c5ccccc5)(c5ccccc5)C=C)([P](c5ccccc5)(c5ccccc5)C=C)[cH]5[cH]1[cH]2[c]13[c]45cccc1
• Title of publication: Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration
• Authors of publication: Garon, Christian N.; McIsaac, Daniel I.; Vogels, Christopher M.; Decken, Andreas; Williams, Ian D.; Kleeberg, Christian; Marder, Todd B.; Westcott, Stephen A.
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 9
• Pages of publication: 1624 - 1631
• a: 17.385 ± 0.004 Å
• b: 10.162 ± 0.002 Å
• c: 17.492 ± 0.004 Å
• α: 90°
• β: 103.055 ± 0.004°
• γ: 90°
• Cell volume: 3010.4 ± 1.1 ų
• Cell temperature: 173 ± 1 K
• Ambient diffraction temperature: 173 ± 1 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0915
• Residual factor for significantly intense reflections: 0.0477
• Weighted residual factors for significantly intense reflections: 0.1055
• Weighted residual factors for all reflections included in the refinement: 0.1374
• Goodness-of-fit parameter for all reflections included in the refinement: 1.098
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No