Information card for entry 7003527

Structure parameters

• Common name: ((tmeda)Li(Me3SiNCPhCHC(NSiMe3)C6H4C(NSiMe3)NCPhCHSiMe3)Li(tmeda))
• Formula: C48 H84 Li2 N8 Si4
• Calculated formula: C48 H84 Li2 N8 Si4
• SMILES: [Li]12([N]([Si](C)(C)C)=C(C=C(N1[Si](C)(C)C)c1cc(ccc1)C1=[N]([Li]3(N1C(=C[Si](C)(C)C)c1ccccc1)[N](CC[N]3(C)C)(C)C)[Si](C)(C)C)c1ccccc1)[N](CC[N]2(C)C)(C)C
• Title of publication: Synthesis and structures of some new types of lithium β-diketiminates
• Authors of publication: Wei, Xue-Hong; Farwell, James D.; Hitchcock, Peter B.; Lappert, Michael F.
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 8
• Pages of publication: 1073 - 1080
• a: 18.5001 ± 0.0003 Å
• b: 14.7798 ± 0.0003 Å
• c: 21.7209 ± 0.0005 Å
• α: 90°
• β: 98.215 ± 0.001°
• γ: 90°
• Cell volume: 5878.2 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0819
• Residual factor for significantly intense reflections: 0.0605
• Weighted residual factors for significantly intense reflections: 0.1424
• Weighted residual factors for all reflections included in the refinement: 0.1577
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No