Information card for entry 7003889

Structure parameters

• Common name: W(N=PCl3)(Cl)2(N(i-Pr)Ar)3
• Formula: C37 H56 Cl5 N4 O P W
• Calculated formula: C37 H56 Cl5 N4 O P W
• Title of publication: 6-Coordinate tungsten(vi) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles
• Authors of publication: Clough, Christopher R.; Müller, Peter; Cummins, Christopher C.
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 33
• Pages of publication: 4458 - 4463
• a: 15.9389 ± 0.0006 Å
• b: 13.7357 ± 0.0005 Å
• c: 18.9527 ± 0.0006 Å
• α: 90°
• β: 97.462 ± 0.001°
• γ: 90°
• Cell volume: 4114.2 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0436
• Residual factor for significantly intense reflections: 0.0332
• Weighted residual factors for significantly intense reflections: 0.0839
• Weighted residual factors for all reflections included in the refinement: 0.0895
• Goodness-of-fit parameter for all reflections included in the refinement: 1.068
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No