Information card for entry 7004854

Structure parameters

• Common name: trans(Cl,Cl)cis(P,P)-dichlorobis((3- aminopropyl)dimethylphosphine)cobalt(iii) hexafluorophosphate
• Chemical name: trans(Cl,Cl)cis(P,P)-dichlorobis((3-aminopropyl)dimethylphosphine)cobalt(III) hexafluorophosphate
• Formula: C10 H28 Cl2 Co F6 N2 P3
• Calculated formula: C10 H28 Cl2 Co F6 N2 P3
• SMILES: [Co]12(Cl)(Cl)([P](C)(C)CCC[NH2]1)[P](C)(C)CCC[NH2]2.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Preparation and characterization of mixed-ligand cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp). Conformation of the six-membered pdmp chelate ring.
• Authors of publication: Suzuki, Takayoshi; Fujiiwara, Katsuhiro; Takagi, Hideo D.; Kashiwabara, Kazuo
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 3
• Pages of publication: 308 - 319
• a: 8.178 ± 0.011 Å
• b: 10.073 ± 0.013 Å
• c: 12.811 ± 0.016 Å
• α: 105.659 ± 0.012°
• β: 94.09 ± 0.02°
• γ: 98.15 ± 0.02°
• Cell volume: 999 ± 2 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.059
• Residual factor for significantly intense reflections: 0.0421
• Weighted residual factors for significantly intense reflections: 0.0908
• Weighted residual factors for all reflections included in the refinement: 0.0985
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No