Information card for entry 7006328

Structure parameters

• Common name: ((Na(NCAd)(Me3SiNSiMe3))2)
• Formula: C34 H66 N4 Na2 Si4
• Calculated formula: C34 H66 N4 Na2 Si4
• SMILES: [Na]1([N]([Na]([N]1([Si](C)(C)C)[Si](C)(C)C)[N]#CC12CC3CC(C1)CC(C2)C3)([Si](C)(C)C)[Si](C)(C)C)[N]#CC12CC3CC(C1)CC(C2)C3
• Title of publication: Reactions between a sodium amide Na[N(SiMe3)R1] (R1 = SiMe3, SiMe2Ph or But) and a cyanoalkane RCN (R = Ad or Bu(t)).
• Authors of publication: Avent, Anthony G.; Antolini, Floria; Hitchcock, Peter B.; Khvostov, Alexei V.; Lappert, Michael F.; Protchenko, Andrey V.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 7
• Pages of publication: 919 - 927
• a: 9.884 ± 0.0004 Å
• b: 9.9561 ± 0.0002 Å
• c: 22.0449 ± 0.0008 Å
• α: 84.169 ± 0.002°
• β: 85.751 ± 0.002°
• γ: 81.851 ± 0.002°
• Cell volume: 2132.41 ± 0.12 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0704
• Residual factor for significantly intense reflections: 0.0553
• Weighted residual factors for significantly intense reflections: 0.148
• Weighted residual factors for all reflections included in the refinement: 0.158
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No