Information card for entry 7007387

Structure parameters

• Formula: C108 H120 F10 P4 Pt2
• Calculated formula: C108 H94 F10 P4 Pt2
• SMILES: [Pt]123([P](CCCCCCCCCCCCCCCCCCCC[P]([Pt]2([P](CCCCCCCCCCCCCCCCCCCC[P]3(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(C#CC#CC#CC#C1)c1c(F)c(F)c(F)c(F)c1F)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Wire-like PtC[triple bond]CC[triple bond]CC[triple bond]CC[triple bond]CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P linkages.
• Authors of publication: de Quadras, Laura; Hampel, Frank; Gladysz, J. A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 24
• Pages of publication: 2929 - 2933
• a: 39.9137 ± 0.0006 Å
• b: 11.1431 ± 0.0002 Å
• c: 22.6389 ± 0.0004 Å
• α: 90°
• β: 102.57 ± 0.03°
• γ: 90°
• Cell volume: 9827.6 ± 1.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0771
• Residual factor for significantly intense reflections: 0.0421
• Weighted residual factors for significantly intense reflections: 0.099
• Weighted residual factors for all reflections included in the refinement: 0.1123
• Goodness-of-fit parameter for all reflections included in the refinement: 0.991
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No