Information card for entry 7007388

Structure parameters

• Formula: C97 H100 F10 O5 P4 Pt2
• Calculated formula: C97 H100 F10 O5 P4 Pt2
• SMILES: [Pt]12([P](CCCCOCCCCCCOCCCC[P]([Pt]([P](CCCCOCCCCCCOCCCC[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(C#CC#CC#CC#C1)c1c(F)c(F)c(F)c(F)c1F)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)c1c(F)c(F)c(F)c(F)c1F.OC
• Title of publication: Wire-like PtC[triple bond]CC[triple bond]CC[triple bond]CC[triple bond]CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P linkages.
• Authors of publication: de Quadras, Laura; Hampel, Frank; Gladysz, J. A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 24
• Pages of publication: 2929 - 2933
• a: 21.4114 ± 0.0003 Å
• b: 17.9695 ± 0.0003 Å
• c: 24.2342 ± 0.0003 Å
• α: 90°
• β: 101.855 ± 0.001°
• γ: 90°
• Cell volume: 9125.3 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0886
• Residual factor for significantly intense reflections: 0.0421
• Weighted residual factors for significantly intense reflections: 0.0848
• Weighted residual factors for all reflections included in the refinement: 0.0979
• Goodness-of-fit parameter for all reflections included in the refinement: 0.966
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No