Information card for entry 7008377

Structure parameters

• Chemical name: dichloro-(bis(1,2-diphenylarsino)ethane)-platinum(ii) acetone solvate
• Formula: C29 H30 As2 Cl2 O Pt
• Calculated formula: C29 H30 As2 Cl2 O Pt
• SMILES: [Pt]1([As](c2ccccc2)(c2ccccc2)CC[As]1(c1ccccc1)c1ccccc1)(Cl)Cl.CC(=O)C
• Title of publication: Influence of the terminal ligands on the redox properties of the {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As) complexes and on their reactivity towards metal centres, protic acids and organic electrophiles.
• Authors of publication: Novio, Fernando; Mas-Ballesté, Rubén; Gallardo, Iluminada; González-Duarte, Pilar; Lledós, Agustí; Vila, Neus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 16
• Pages of publication: 2742 - 2753
• a: 9.224 ± 0.002 Å
• b: 13.906 ± 0.003 Å
• c: 21.742 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2788.8 ± 1.1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0382
• Residual factor for significantly intense reflections: 0.0277
• Weighted residual factors for significantly intense reflections: 0.0573
• Weighted residual factors for all reflections included in the refinement: 0.0619
• Goodness-of-fit parameter for all reflections included in the refinement: 1.095
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No