Information card for entry 7008382

Structure parameters

• Common name: tetrakis((mu!3$-Sulfido)-(1,2-bis(diphenylarsino)ethane)- platinum)-cadmium(ii) diperchlorate ethanol water solvate
• Chemical name: tetrakis((μ~3~-Sulfido)-(1,2-bis(diphenylarsino)ethane)-platinum)-cadmium(ii) diperchlorate ethanol water solvate
• Formula: C109 H113 As8 Cd Cl2 O11.5 Pt4 S4
• Calculated formula: C108.75 H110 As8 Cd Cl2 O11 Pt4 S4
• Title of publication: Influence of the terminal ligands on the redox properties of the {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As) complexes and on their reactivity towards metal centres, protic acids and organic electrophiles.
• Authors of publication: Novio, Fernando; Mas-Ballesté, Rubén; Gallardo, Iluminada; González-Duarte, Pilar; Lledós, Agustí; Vila, Neus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 16
• Pages of publication: 2742 - 2753
• a: 23.387 ± 0.006 Å
• b: 18.798 ± 0.005 Å
• c: 51.687 ± 0.014 Å
• α: 90°
• β: 96.543 ± 0.005°
• γ: 90°
• Cell volume: 22575 ± 10 ų
• Cell temperature: 120 ± 0.1 K
• Ambient diffraction temperature: 120 ± 0.1 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1154
• Residual factor for significantly intense reflections: 0.0873
• Weighted residual factors for significantly intense reflections: 0.1744
• Weighted residual factors for all reflections included in the refinement: 0.1847
• Goodness-of-fit parameter for all reflections included in the refinement: 1.203
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No