Information card for entry 7008383

Structure parameters

• Chemical name: bis(μ~3~-Sulfido)-tris((1,2-bis(diphenylarsino)ethane)-platinum) bis(tetraphenylborate) dimethylsulfoxide solvate
• Formula: C130 H124 As6 B2 O2 Pt3 S4
• Calculated formula: C130 H124 As6 B2 O2 Pt3 S4
• SMILES: [Pt]12([As](CC[As]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[S]1[Pt]3([As](CC[As]3(c3ccccc3)c3ccccc3)(c3ccccc3)c3ccccc3)[S]2[Pt]12[As](CC[As]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.S(=O)(C)C.S(=O)(C)C
• Title of publication: Influence of the terminal ligands on the redox properties of the {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As) complexes and on their reactivity towards metal centres, protic acids and organic electrophiles.
• Authors of publication: Novio, Fernando; Mas-Ballesté, Rubén; Gallardo, Iluminada; González-Duarte, Pilar; Lledós, Agustí; Vila, Neus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 16
• Pages of publication: 2742 - 2753
• a: 14.306 ± 0.003 Å
• b: 15.391 ± 0.003 Å
• c: 29.884 ± 0.006 Å
• α: 91.679 ± 0.004°
• β: 99.603 ± 0.004°
• γ: 116.255 ± 0.003°
• Cell volume: 5779 ± 2 ų
• Cell temperature: 120 ± 0.1 K
• Ambient diffraction temperature: 120 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0502
• Residual factor for significantly intense reflections: 0.032
• Weighted residual factors for significantly intense reflections: 0.0665
• Weighted residual factors for all reflections included in the refinement: 0.0729
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No