Information card for entry 7008452

Structure parameters

• Formula: C24 H26 Cl2 N3 P Pt
• Calculated formula: C24 H26 Cl2 N3 P Pt
• SMILES: [Pt](Cl)(Cl)([N]#CCC)[NH]=C(N=P(c1ccccc1)(c1ccccc1)c1ccccc1)CC
• Title of publication: The first examples of metal-mediated addition of a phosphorus imine to nitriles; the preparation and X-ray crystal structures of [PtCl4{NH=C(Et)N=PPh3}2] and [PtCl2(EtCN){NH=C(Et)N[double bond, length as m-dash]PPh3}].
• Authors of publication: Bokach, Nadezhda A.; Kukushkin, Vadim Yu; Kelly, Paul F.; Haukka, Matti; Pombeiro, Armando J. L.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 8
• Pages of publication: 1354 - 1356
• a: 22.0217 ± 0.0003 Å
• b: 8.7854 ± 0.0005 Å
• c: 24.7704 ± 0.001 Å
• α: 90°
• β: 90.045 ± 0.003°
• γ: 90°
• Cell volume: 4792.3 ± 0.3 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0494
• Residual factor for significantly intense reflections: 0.0325
• Weighted residual factors for significantly intense reflections: 0.0625
• Weighted residual factors for all reflections included in the refinement: 0.0675
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No