Information card for entry 7008717

Structure parameters

• Formula: C44 H68 Cr2 N4 O2 Si4
• Calculated formula: C44 H68 Cr2 N4 O2 Si4
• SMILES: [Cr]1234[Cr]56([N]1(c1c(cc(cc1C)C)C)[Si]([O]5[Si](N6c1c(cc(cc1C)C)C)(C)C)(C)C)[N]4([Si]([O]3[Si](N2c1c(cc(cc1C)C)C)(C)C)(C)C)c1c(cc(cc1C)C)C
• Title of publication: Synthesis of mixed-donor amido/amino/siloxo ligands from symmetrical diamidosilylether ligands via a retro-Brook rearrangement and their chromium(ii) complexes
• Authors of publication: Haftbaradaran, Farzad; Mund, Garry; Batchelor, Raymond J.; Britten, James F.; Leznoff, Daniel B.
• Journal of publication: Dalton Transactions
• Year of publication: 2005
• Journal issue: 14
• Pages of publication: 2343
• a: 11.349 ± 0.003 Å
• b: 11.513 ± 0.003 Å
• c: 20.346 ± 0.004 Å
• α: 105.8 ± 0.018°
• β: 95.03 ± 0.02°
• γ: 103.31 ± 0.02°
• Cell volume: 2457 ± 1.1 ų
• Cell temperature: 293 K
• Ambient diffraction temperature: 293 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1737
• Residual factor for significantly intense reflections: 0.0575
• Weighted residual factors for all reflections: 0.0557
• Weighted residual factors for significantly intense reflections: 0.052
• Weighted residual factors for all reflections included in the refinement: 0.052
• Goodness-of-fit parameter for all reflections included in the refinement: 2.392
• Diffraction radiation wavelength: 0.7093 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No