Structural and electronic impact of fluorine in the ortho positions of triphenylphosphine and 1,2-bis(diphenylphosphino)ethane; a comparison of 2,6-difluorophenyl- with pentafluorophenyl-phosphines
Authors of publication
Corcoran, Christopher; Fawcett, John; Friedrichs, Steffi; Holloway, John H.; Hope, Eric G.; Russell, David R.; Saunders, Graham C.; Stuart, Alison M.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2000
Journal issue
2
Pages of publication
161
a
16.312 ± 0.004 Å
b
12.303 ± 0.004 Å
c
16.451 ± 0.004 Å
α
90°
β
90°
γ
90°
Cell volume
3301.5 ± 1.6 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
6
Space group number
61
Hermann-Mauguin space group symbol
P b c a
Hall space group symbol
-P 2ac 2ab
Residual factor for all reflections
0.1469
Residual factor for significantly intense reflections
0.0459
Weighted residual factors for all reflections
0.099
Weighted residual factors for significantly intense reflections
0.0723
Goodness-of-fit parameter for all reflections
0.971
Goodness-of-fit parameter for significantly intense reflections
