Information card for entry 7009026

Structure parameters

• Chemical name: mer-cis-trichloro diammine dimethylsulfide osmium(III)
• Formula: C2 H12 Cl3 N2 Os S
• Calculated formula: C2 H12 Cl3 N2 Os S
• SMILES: [Os](Cl)(Cl)(Cl)([S](C)C)([NH3])[NH3]
• Title of publication: Unusual pathways for the reaction between [MCl2(Me2SO)4] (M = Os, Ru) and hydrazine dihydrochloride: deoxygenation of sulfoxides vs. coordination of hydrazinium
• Authors of publication: da Silva, M. Fátima C. Guedes; Pombeiro, Armando J. L.; Geremia, Silvano; Zangrando, Ennio; Calligaris, Mario; Zinchenko, Andrey V.; Kukushkin, Vadim Yu.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 8
• Pages of publication: 1363
• a: 9.5765 ± 0.001 Å
• b: 8.9186 ± 0.0008 Å
• c: 11.8001 ± 0.0009 Å
• α: 90°
• β: 99.43 ± 0.01°
• γ: 90°
• Cell volume: 994.22 ± 0.16 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0336
• Residual factor for significantly intense reflections: 0.0291
• Weighted residual factors for all reflections: 0.0787
• Weighted residual factors for significantly intense reflections: 0.0771
• Goodness-of-fit parameter for all reflections: 1.059
• Goodness-of-fit parameter for significantly intense reflections: 1.099
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No