Information card for entry 7009028

Structure parameters

• Chemical name: mer-cis-trichloro dis(dimethylsulfoxide) hydrazinium ruthenium(II)
• Formula: C4 H17 Cl3 N2 O2 Ru S2
• Calculated formula: C4 H17 Cl3 N2 O2 Ru S2
• SMILES: [Ru](Cl)(Cl)(Cl)([S](=O)(C)C)([S](=O)(C)C)[NH2][NH3+]
• Title of publication: Unusual pathways for the reaction between [MCl2(Me2SO)4] (M = Os, Ru) and hydrazine dihydrochloride: deoxygenation of sulfoxides vs. coordination of hydrazinium
• Authors of publication: da Silva, M. Fátima C. Guedes; Pombeiro, Armando J. L.; Geremia, Silvano; Zangrando, Ennio; Calligaris, Mario; Zinchenko, Andrey V.; Kukushkin, Vadim Yu.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 8
• Pages of publication: 1363
• a: 26.202 ± 0.004 Å
• b: 8.455 ± 0.001 Å
• c: 12.918 ± 0.002 Å
• α: 90°
• β: 106.55 ± 0.01°
• γ: 90°
• Cell volume: 2743.3 ± 0.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0266
• Residual factor for significantly intense reflections: 0.0247
• Weighted residual factors for significantly intense reflections: 0.0703
• Weighted residual factors for all reflections included in the refinement: 0.0715
• Goodness-of-fit parameter for all reflections included in the refinement: 1.09
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No