Information card for entry 7009042

Structure parameters

• Formula: C32 H32 F24 N4 Na4 O8
• Calculated formula: C32 H32 F24 N4 Na4 O8
• SMILES: [Na]1234[O]56[Na]789[O]%10%11[Na]6%12([O]2(C(=CC(=[N]4CC[O]1C)C(F)(F)F)C(F)(F)F)[Na]%111([O](C)CC[N]1=C(C(F)(F)F)C=C%10C(F)(F)F)[O]37C(=CC(=[N]8CC[O]9C)C(F)(F)F)C(F)(F)F)[O](C)CC[N]%12=C(C(F)(F)F)C=C5C(F)(F)F
• Title of publication: Synthesis and characterization of two novel tetranuclear sodium ketoiminate complexes; structural evidence for formation of dative Na · · · F and Na–C (olefin) bonding interactions
• Authors of publication: Chi, Yun; Ranjan, Sudhir; Chung, Po-Wen; Liu, Chao-Shiuan; Peng, Shie-Ming; Lee, Gene-Hsiang
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 3
• Pages of publication: 343
• a: 10.402 ± 0.003 Å
• b: 13.806 ± 0.003 Å
• c: 18.819 ± 0.005 Å
• α: 83.85 ± 0.04°
• β: 77.08 ± 0.04°
• γ: 70.04 ± 0.03°
• Cell volume: 2474.5 ± 1.3 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.145
• Residual factor for significantly intense reflections: 0.0716
• Weighted residual factors for all reflections: 0.2469
• Weighted residual factors for significantly intense reflections: 0.2107
• Goodness-of-fit parameter for all reflections: 1.032
• Goodness-of-fit parameter for significantly intense reflections: 1.377
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No