Information card for entry 7009043

Structure parameters

• Formula: C32 H24 F24 N4 Na4 O4
• Calculated formula: C32 H24 F24 N4 Na4 O4
• SMILES: C=CC[N]1=C(C(F)(F)F)C=C(C(F)(F)F)[O]23[Na]451[O]16C(=CC(=[N](CC=C)[Na]21[O]12C7=CC(=[N](CC=C)[Na]861[O]14C(=CC(=[N]([Na]321[F]C7(F)F)CC=C)C(F)(F)F)C(F)([F]8)F)C(F)(F)F)C(F)(F)F)C(F)(F)[F]5
• Title of publication: Synthesis and characterization of two novel tetranuclear sodium ketoiminate complexes; structural evidence for formation of dative Na · · · F and Na‒C (olefin) bonding interactions
• Authors of publication: Chi, Yun; Ranjan, Sudhir; Chung, Po-Wen; Liu, Chao-Shiuan; Peng, Shie-Ming; Lee, Gene-Hsiang
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 3
• Pages of publication: 343
• a: 13.6765 ± 0.0002 Å
• b: 21.6103 ± 0.0002 Å
• c: 16.0552 ± 0.0003 Å
• α: 90°
• β: 113.605 ± 0.001°
• γ: 90°
• Cell volume: 4348.13 ± 0.12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.088
• Residual factor for significantly intense reflections: 0.0564
• Weighted residual factors for all reflections: 0.1374
• Weighted residual factors for significantly intense reflections: 0.1222
• Goodness-of-fit parameter for all reflections: 1.035
• Goodness-of-fit parameter for significantly intense reflections: 1.12
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No