Information card for entry 7009473

Structure parameters

• Formula: C35.5 H58 Li N8 S2 Sb3
• Calculated formula: C35.5 H54 Li N8 S2 Sb3
• Title of publication: Reactions of the spiro monoanion [{(Me2N)Sb(μ-NCy)2}2Sb]− with alcohols and thiols (REH; E = O or S); syntheses of nido-[Sb3(μ-NCy)3(μ3-NCy)(ER)2] anions and the unique antimony(III) imido cubane [(2-NC5H4O)Sb(μ3-NCy)]4 (Cy= cyclohexyl)
• Authors of publication: Bashall, Alan; Beswick, Michael A.; Feeder, Neil; Hopkins, Alexander D.; Kidd, Sara J.; McPartlin, Mary; Raithby, Paul R.; Wright, Dominic S.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 12
• Pages of publication: 1841
• a: 11.177 ± 0.003 Å
• b: 13.746 ± 0.003 Å
• c: 15.173 ± 0.004 Å
• α: 70.146 ± 0.01°
• β: 87.83 ± 0.02°
• γ: 89.668 ± 0.019°
• Cell volume: 2191 ± 1 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1047
• Residual factor for significantly intense reflections: 0.0616
• Weighted residual factors for significantly intense reflections: 0.1645
• Weighted residual factors for all reflections included in the refinement: 0.205
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No