Information card for entry 7009475

Structure parameters

• Formula: C28 H56 N6 Na Sb3
• Calculated formula: C28 H56 N6 Na Sb3
• SMILES: [Sb]12N(C3CCCCC3)[Sb]34N(C5CCCCC5)[Sb]5[N](C)(C)[Na]([N]35C3CCCCC3)([N]14C1CCCCC1)[N]2(C)C
• Title of publication: Reactions of the spiro monoanion [{(Me2N)Sb(μ-NCy)2}2Sb]− with alcohols and thiols (REH; E = O or S); syntheses of nido-[Sb3(μ-NCy)3(μ3-NCy)(ER)2] anions and the unique antimony(III) imido cubane [(2-NC5H4O)Sb(μ3-NCy)]4 (Cy= cyclohexyl)
• Authors of publication: Bashall, Alan; Beswick, Michael A.; Feeder, Neil; Hopkins, Alexander D.; Kidd, Sara J.; McPartlin, Mary; Raithby, Paul R.; Wright, Dominic S.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 12
• Pages of publication: 1841
• a: 9.599 ± 0.002 Å
• b: 21.379 ± 0.004 Å
• c: 17.097 ± 0.003 Å
• α: 90°
• β: 99.82 ± 0.03°
• γ: 90°
• Cell volume: 3457.2 ± 1.2 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1155
• Residual factor for significantly intense reflections: 0.0787
• Weighted residual factors for significantly intense reflections: 0.1986
• Weighted residual factors for all reflections included in the refinement: 0.2259
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No