Information card for entry 7009715

Structure parameters

• Formula: C75.5 H77 Ag2 O11 P3 Re2
• Calculated formula: C75.5 H77 Ag2 O11 P3 Re2
• SMILES: [Re]1([Ag]2([Ag]([Re]([P]1(C1CCCCC1)C1CCCCC1)(C#[O])(C#[O])(C#[O])OC(=[O]2)[C@@]12OC(=O)[C@@](CC1)(C2(C)C)C)[P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])(C#[O])C#[O].Cc1ccccc1.Cc1ccccc1
• Title of publication: Diastereomeric metallatetrahedron complexes of the type Re2(AgPR3)2(μ-PCy2)(CO)7Z (R = Et and Ph; Z = (−)- and (+)-camphanate): synthesis, structure and CD data
• Authors of publication: Haupt, Hans-Jürgen; Seewald, Oliver; Flörke, Ulrich; Buß, Volker; Weyhermüller, Thomas
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 16
• Pages of publication: 2837
• a: 14.374 ± 0.001 Å
• b: 16.115 ± 0.001 Å
• c: 16.641 ± 0.001 Å
• α: 98.12 ± 0.01°
• β: 98.35 ± 0.01°
• γ: 101.83 ± 0.01°
• Cell volume: 3674.1 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0997
• Residual factor for significantly intense reflections: 0.0478
• Weighted residual factors for significantly intense reflections: 0.0909
• Weighted residual factors for all reflections included in the refinement: 0.1001
• Goodness-of-fit parameter for all reflections included in the refinement: 0.935
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No