Structures and spectra of bis-tripodal iron(II) chelates, [FeL2]2+, where L = tris(pyrazol-1-yl)methane, tris(pyridin-2-yl)methane, bis(pyrazol-1-yl)(pyridin-2-yl)methane and tris(pyridin-2-yl)phosphine oxide. Magnetism and spin crossover in the (pz)3CH case
Authors of publication
Anderson, Peter A.; Astley, Timothy; Hitchman, Michael A.; Keene, F. Richard; Moubaraki, Boujemaa; Murray, Keith S.; Skelton, Brian W.; Tiekink, Edward R. T.; Toftlund, Hans; White, Allan H.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2000
Journal issue
20
Pages of publication
3505
a
8.539 ± 0.004 Å
b
10.405 ± 0.004 Å
c
16.5 ± 0.01 Å
α
90°
β
102.99 ± 0.04°
γ
90°
Cell volume
1428.5 ± 1.2 Å3
Cell temperature
293 K
Ambient diffraction temperature
293 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for significantly intense reflections
0.0371
Weighted residual factors for significantly intense reflections
0.0438
Goodness-of-fit parameter for significantly intense reflections
