Structures and spectra of bis-tripodal iron(II) chelates, [FeL2]2+, where L = tris(pyrazol-1-yl)methane, tris(pyridin-2-yl)methane, bis(pyrazol-1-yl)(pyridin-2-yl)methane and tris(pyridin-2-yl)phosphine oxide. Magnetism and spin crossover in the (pz)3CH case
Authors of publication
Anderson, Peter A.; Astley, Timothy; Hitchman, Michael A.; Keene, F. Richard; Moubaraki, Boujemaa; Murray, Keith S.; Skelton, Brian W.; Tiekink, Edward R. T.; Toftlund, Hans; White, Allan H.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2000
Journal issue
20
Pages of publication
3505
a
11.129 ± 0.003 Å
b
13.699 ± 0.003 Å
c
11.239 ± 0.003 Å
α
90°
β
92.04 ± 0.02°
γ
90°
Cell volume
1712.4 ± 0.8 Å3
Cell temperature
293 K
Ambient diffraction temperature
293 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for significantly intense reflections
0.048
Weighted residual factors for significantly intense reflections
0.054
Goodness-of-fit parameter for significantly intense reflections
