Information card for entry 7010190

Structure parameters

• Chemical name: (mu2-hydrido)(tri(phenyl)phosphine)bis(mu2-carbonyl)(octacarbonyl) tri-osmium(cyclopentadienyl)ruthenium
• Formula: C33 H21 O10 Os3 P Ru
• Calculated formula: C33 H21 O10 Os3 P Ru
• SMILES: [Os]12([Os]345([H][Os]561([Ru]178923(C4=O)(C6=O)[cH]2[cH]1[cH]9[cH]7[cH]82)([P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Use of the monocationic fragment [Ru(η5-C5H5)(MeCN)3]+ as an ionic coupling reagent in the synthesis of mixed-metal phosphine clusters †
• Authors of publication: Buntem, Radchada; Gallagher, John F.; Lewis, Jack; Raithby, Paul R.; Rennie, Moira-Ann; Shields, Gregory P.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 23
• Pages of publication: 4297
• a: 9.213 ± 0.005 Å
• b: 15.832 ± 0.008 Å
• c: 11.821 ± 0.006 Å
• α: 90°
• β: 106.31 ± 0.02°
• γ: 90°
• Cell volume: 1654.8 ± 1.5 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0333
• Residual factor for significantly intense reflections: 0.0332
• Weighted residual factors for all reflections: 0.089
• Weighted residual factors for significantly intense reflections: 0.0889
• Goodness-of-fit parameter for all reflections: 1.043
• Goodness-of-fit parameter for significantly intense reflections: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No