Information card for entry 7010191

Structure parameters

• Formula: C34 H21 O11 Os3 P Ru
• Calculated formula: C34 H21 O11 Os3 P Ru
• SMILES: [Os]123([Os]4([H][OsH]14([Ru]14562([cH]2[cH]1[cH]4[cH]5[cH]62)(C3=O)C#[O])(C#[O])(C#[O])C#[O])([P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Use of the monocationic fragment [Ru(η5-C5H5)(MeCN)3]+ as an ionic coupling reagent in the synthesis of mixed-metal phosphine clusters †
• Authors of publication: Buntem, Radchada; Gallagher, John F.; Lewis, Jack; Raithby, Paul R.; Rennie, Moira-Ann; Shields, Gregory P.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 23
• Pages of publication: 4297
• a: 8.878 ± 0.004 Å
• b: 22.669 ± 0.017 Å
• c: 9.415 ± 0.004 Å
• α: 90°
• β: 114.06 ± 0.04°
• γ: 90°
• Cell volume: 1730.2 ± 1.8 ų
• Cell temperature: 290 ± 2 K
• Ambient diffraction temperature: 290 ± 2 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0494
• Residual factor for significantly intense reflections: 0.0462
• Weighted residual factors for all reflections: 0.108
• Weighted residual factors for significantly intense reflections: 0.1055
• Goodness-of-fit parameter for all reflections: 1.175
• Goodness-of-fit parameter for significantly intense reflections: 1.178
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No