Information card for entry 7010364

Structure parameters

• Chemical name: dichloro-di-μ-chlorobis(2-methylphenylimido)tetrakis- pyridinedititanium(IV) dichloromethane solvate
• Formula: C18 H18 Cl4 N3 Ti
• Calculated formula: C18 H18 Cl4 N3 Ti
• Title of publication: 2-tert-Butyl and 2-phenylphenylimido complexes of titanium(IV) and their olefin polymerisation activity
• Authors of publication: Nielson, Alastair J.; Glenny, Mark W.; Rickard, Clifton E. F.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 3
• Pages of publication: 232
• a: 9.903 ± 0.00009 Å
• b: 15.9595 ± 0.0002 Å
• c: 13.5773 ± 0.0001 Å
• α: 90°
• β: 101.159 ± 0.001°
• γ: 90°
• Cell volume: 2105.28 ± 0.04 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0366
• Weighted residual factors for significantly intense reflections: 0.0884
• Weighted residual factors for all reflections included in the refinement: 0.0948
• Goodness-of-fit parameter for all reflections included in the refinement: 1.068
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No