Information card for entry 7010365

Structure parameters

• Chemical name: dichloro-di-μ-chloro(2-t-butylphenylimido)tetrakis- pyridinedititanium(IV) bis(dichloromethane) solvate
• Formula: C22 H27 Cl6 N3 Ti
• Calculated formula: C22 H27 Cl6 N3 Ti
• Title of publication: 2-tert-Butyl and 2-phenylphenylimido complexes of titanium(IV) and their olefin polymerisation activity
• Authors of publication: Nielson, Alastair J.; Glenny, Mark W.; Rickard, Clifton E. F.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 3
• Pages of publication: 232
• a: 8.042 Å
• b: 10.7341 ± 0.0001 Å
• c: 16.4281 ± 0.0002 Å
• α: 77.013 ± 0.001°
• β: 77.14 ± 0.0009°
• γ: 84.59 ± 0.001°
• Cell volume: 1345.73 ± 0.02 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0638
• Residual factor for significantly intense reflections: 0.0552
• Weighted residual factors for significantly intense reflections: 0.1548
• Weighted residual factors for all reflections included in the refinement: 0.1615
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No