Information card for entry 7011454

Structure parameters

• Formula: C56 H44 O6 P4 Pt2 Rh2
• Calculated formula: C56 H44 O6 P4 Pt2 Rh2
• SMILES: [Pt]123[Rh]4([Pt]567C#[O])([Rh]51([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C6=O)(C4=O)C#[O])([P](C[P]3(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C7=O)C#[O]
• Title of publication: Synthesis and structural characterization of mixed-metal Pt‒Rh clusters. Assembly of tetra- and tetra-hexanuclear clusters from smaller metal fragments
• Authors of publication: Koshevoy, Igor O.; Tunik, Sergey P.; Jääskeläinen, Sirpa; Haukka, Matti; Pakkanen, Tapani A.; Podkorytov, Ivan S.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 13
• Pages of publication: 2768
• a: 11.8198 ± 0.0004 Å
• b: 12.5681 ± 0.0005 Å
• c: 18.0603 ± 0.0007 Å
• α: 104.37 ± 0.002°
• β: 92.979 ± 0.001°
• γ: 95.595 ± 0.001°
• Cell volume: 2578.5 ± 0.17 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0437
• Residual factor for significantly intense reflections: 0.0342
• Weighted residual factors for significantly intense reflections: 0.0742
• Weighted residual factors for all reflections included in the refinement: 0.0783
• Goodness-of-fit parameter for all reflections included in the refinement: 1.128
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No