Information card for entry 7011817

Structure parameters

• Formula: C58 H74 Ge O4 Si6
• Calculated formula: C58 H74 Ge O4 Si6
• Title of publication: Novel germanium(ii) binaphthoxide complexes: synthesis and crystal structure of (R,R)-[Ge{OC20H10(OSiMe3)-2'-(SiMe3)2-3,3'}2] and (R)-[Ge{O2C20H10(SiMe2Ph)2-3,3'}{NH3}]; catalytic function of Ge[N(SiMe3)2]2 for the mono-silylation of 3,3'-disubstituted-1,1'-bi-2,2'-naphthols
• Authors of publication: Weinert, Charles S.; Fanwick, Phillip E.; Rothwell, Ian P.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 15
• Pages of publication: 2948
• a: 11.0695 ± 0.0002 Å
• b: 21.0832 ± 0.0004 Å
• c: 12.8046 ± 0.0003 Å
• α: 90°
• β: 99.7418 ± 0.0008°
• γ: 90°
• Cell volume: 2945.25 ± 0.1 ų
• Cell temperature: 149 K
• Ambient diffraction temperature: 149 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for significantly intense reflections: 0.037
• Weighted residual factors for all reflections included in the refinement: 0.082
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MO-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No