Information card for entry 7011975

Structure parameters

• Formula: C32 H32 As2 F6 N4 O6 Ru S2
• Calculated formula: C32 H32 As2 F6 N4 O6 Ru S2
• SMILES: [As]1(C)(C)c2ccccc2[As](C)(C)[Ru]231([n]1ccccc1c1cccc[n]21)[n]1ccccc1c1cccc[n]31.C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-]
• Title of publication: Syntheses, characterization and redox properties of homoleptic ruthenium(II)‒diphosphine and diarsine complexes: deviations from ligand additivity
• Authors of publication: Annemarie A. La Pensée; Jamie Bickley; Simon J. Higgins; Massimo Marcaccio; Francesco Paolucci; Sergio Roffia; John M. Charnock
• Journal of publication: J. Chem. Soc., Dalton Trans.
• Year of publication: 2002
• Journal issue: 22
• Pages of publication: 4095 - 4104
• a: 19.422 ± 0.0014 Å
• b: 13.4406 ± 0.001 Å
• c: 28.171 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7353.9 ± 0.9 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0266
• Residual factor for significantly intense reflections: 0.024
• Weighted residual factors for significantly intense reflections: 0.0598
• Weighted residual factors for all reflections included in the refinement: 0.0607
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No