Structures and reactions of monomeric and dimeric lithium diazapentadienyl complexes with electrophiles: synthesis of α-C,C'-dialkyl-β-diimines, and dissolution-reversible synthesis of an α-alkoxylithium-β-diimine
Authors of publication
Carey, David T.; Cope-Eatough, Elaine K.; Vilaplana-Mafé, Eva; Mair, Francis S.; Pritchard, Robin G.; Warren, John E.; Woods, Rebecca J.
Journal of publication
Dalton Transactions
Year of publication
2003
Journal issue
6
Pages of publication
1083
a
11.5857 ± 0.001 Å
b
9.3714 ± 0.001 Å
c
26.8363 ± 0.001 Å
α
90°
β
92.389 ± 0.01°
γ
90°
Cell volume
2911.2 ± 0.4 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0984
Residual factor for significantly intense reflections
0.0571
Weighted residual factors for significantly intense reflections
0.1251
Weighted residual factors for all reflections included in the refinement
0.1482
Goodness-of-fit parameter for all reflections included in the refinement
