Information card for entry 7013879

Structure parameters

• Common name: (Co(CO)3(P(N(iPr)2)(N(SiMe3)2)))
• Formula: C15 H32 Co N2 O3 P Si2
• Calculated formula: C15 H32 Co N2 O3 P Si2
• SMILES: [Co](P(N(C(C)C)C(C)C)N([Si](C)(C)C)[Si](C)(C)C)(C#[O])(C#[O])C#[O]
• Title of publication: Synthesis and P-P cleavage reactions of [P(X)X']2; X-ray structures of [Co[P(X)X'](CO)3] and P4[P(X)X']2[X = N(SiMe3)2, X'= NPri2].
• Authors of publication: Bezombes, Jean-Philippe; Hitchcock, Peter B.; Lappert, Michael F.; Nycz, Jacek E.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2004
• Journal issue: 4
• Pages of publication: 499 - 501
• a: 9.719 ± 0.0006 Å
• b: 9.8945 ± 0.0007 Å
• c: 13.6614 ± 0.0012 Å
• α: 88.878 ± 0.004°
• β: 89.121 ± 0.004°
• γ: 61.153 ± 0.004°
• Cell volume: 1150.48 ± 0.15 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1011
• Residual factor for significantly intense reflections: 0.0706
• Weighted residual factors for significantly intense reflections: 0.1735
• Weighted residual factors for all reflections included in the refinement: 0.1904
• Goodness-of-fit parameter for all reflections included in the refinement: 1.104
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No