Information card for entry 7013887

Structure parameters

• Formula: C50 H58 B5 O12 P2 Rh
• Calculated formula: C50 H58 B5 O12 P2 Rh
• SMILES: [Rh]123([P](c4ccccc4)(c4ccccc4)c4ccccc4)([P](c4ccccc4)(c4ccccc4)c4ccccc4)[CH]4=[CH]1CC[CH]2=[CH]3CC4.O1[B]2(OB(OB1O)O)OB(OB(O2)O)O.O=C(C)C.O=C(C)C
• Title of publication: Cationic Rh complexes with novel spiro tetraarylpentaborate anions prepared from arylboronic acids and aryloxorhodium complexes.
• Authors of publication: Nishihara, Yasushi; Nara, Kyoko; Nishide, Yasuhiro; Osakada, Kohtaro
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2004
• Journal issue: 9
• Pages of publication: 1366 - 1375
• a: 19.578 ± 0.008 Å
• b: 9.863 ± 0.005 Å
• c: 27.813 ± 0.006 Å
• α: 90°
• β: 103.15 ± 0.03°
• γ: 90°
• Cell volume: 5230 ± 4 ų
• Cell temperature: 296.1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.056
• Weighted residual factors for all reflections included in the refinement: 0.067
• Goodness-of-fit parameter for all reflections included in the refinement: 0.978
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No