Information card for entry 7014997

Structure parameters

• Common name: (iPr2Im)1(SiHPh2)2Ni(ii)
• Chemical name: (iPr2Im)1(SiHPh2)2Ni(II)
• Formula: C34 H56 N4 Ni O Si2
• Calculated formula: C34 H56 N4 Ni O Si2
• SMILES: [Ni]([SiH2]c1ccccc1)([SiH2]c1ccccc1)(=C1N(C=CN1C(C)C)C(C)C)=C1N(C=CN1C(C)C)C(C)C.O(CC)CC
• Title of publication: Si-H Activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes.
• Authors of publication: Zell, Thomas; Schaub, Thomas; Radacki, Krzysztof; Radius, Udo
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 9
• Pages of publication: 1852 - 1854
• a: 10.608 ± 0.002 Å
• b: 10.799 ± 0.002 Å
• c: 32.098 ± 0.006 Å
• α: 90°
• β: 96.47 ± 0.03°
• γ: 90°
• Cell volume: 3653.6 ± 1.2 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0731
• Residual factor for significantly intense reflections: 0.056
• Weighted residual factors for significantly intense reflections: 0.151
• Weighted residual factors for all reflections included in the refinement: 0.1787
• Goodness-of-fit parameter for all reflections included in the refinement: 1.142
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No