Information card for entry 7014998

Structure parameters

• Common name: (iPr2Im)1(SiMePh2)(H)Ni(ii)
• Chemical name: (iPr2Im)1(SiMePh2)(H)Ni(II)
• Formula: C31 H46 N4 Ni Si
• Calculated formula: C31 H46 N4 Ni Si
• SMILES: [NiH]([Si](C)(c1ccccc1)c1ccccc1)(=C1N(C=CN1C(C)C)C(C)C)=C1N(C=CN1C(C)C)C(C)C
• Title of publication: Si-H Activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes.
• Authors of publication: Zell, Thomas; Schaub, Thomas; Radacki, Krzysztof; Radius, Udo
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 9
• Pages of publication: 1852 - 1854
• a: 9.8713 ± 0.0008 Å
• b: 28.291 ± 0.002 Å
• c: 11.4697 ± 0.0009 Å
• α: 90°
• β: 105.117 ± 0.002°
• γ: 90°
• Cell volume: 3092.3 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0303
• Residual factor for significantly intense reflections: 0.0268
• Weighted residual factors for significantly intense reflections: 0.0685
• Weighted residual factors for all reflections included in the refinement: 0.0707
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No