Information card for entry 7016359

Structure parameters

• Formula: C55 H86 O20 P4 Sn2 W2
• Calculated formula: C55 H86 O20 P4 Sn2 W2
• Title of publication: Intramolecularly coordinated heteroleptic organostannylene tungsten pentacarbonyl complexes 4-tBu-2,6-[P(O)(OiPr)(2)](2)C(6)H(2)Sn(X)W(CO)(5) (X = Cl, F, PPh(2), PPh(2)[W(CO)(5)]). Syntheses and reactivity.
• Authors of publication: Wagner, Michael; Dorogov, Konstantin; Schürmann, Markus; Jurkschat, Klaus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 35
• Pages of publication: 8839 - 8848
• a: 22.0762 ± 0.0009 Å
• b: 12.187 ± 0.0004 Å
• c: 26.8904 ± 0.0011 Å
• α: 90°
• β: 106.306 ± 0.004°
• γ: 90°
• Cell volume: 6943.7 ± 0.5 ų
• Cell temperature: 173 ± 1 K
• Ambient diffraction temperature: 173 ± 1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0934
• Residual factor for significantly intense reflections: 0.0535
• Weighted residual factors for significantly intense reflections: 0.1218
• Weighted residual factors for all reflections included in the refinement: 0.1292
• Goodness-of-fit parameter for all reflections included in the refinement: 0.962
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No