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Information card for entry 7016455
Preview
Coordinates | 7016455.cif |
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Original paper (by DOI) | HTML |
Formula | C55 H47 Ni P3 Si |
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Calculated formula | C55 H47 Ni P3 Si |
SMILES | [Ni]12([P](c3ccccc3)(c3c([Si](c4c([P]1(c1ccccc1)c1ccccc1)cccc4)(C)[H]2)cccc3)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Reaction of bis(o-phosphinophenyl)silane with M(PPh(3))(4) (M = Ni, Pd, Pt): synthesis and structural analysis of η(2)-(Si-H) metal(0) and pentacoordinate silyl metal(ii) hydride complexes of the Ni triad bearing a PSiP-pincer ligand. |
Authors of publication | Takaya, Jun; Iwasawa, Nobuharu |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2011 |
Journal volume | 40 |
Journal issue | 35 |
Pages of publication | 8814 - 8821 |
a | 12.2584 ± 0.0004 Å |
b | 18.3081 ± 0.0008 Å |
c | 19.6284 ± 0.0008 Å |
α | 91.3972 ± 0.0013° |
β | 90.1161 ± 0.0012° |
γ | 90.9045 ± 0.0012° |
Cell volume | 4403.3 ± 0.3 Å3 |
Cell temperature | 173.1 K |
Ambient diffraction temperature | 173.1 K |
Number of distinct elements | 5 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for significantly intense reflections | 0.034 |
Weighted residual factors for all reflections included in the refinement | 0.1229 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.014 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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