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Information card for entry 7016456
Preview
Coordinates | 7016456.cif |
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Original paper (by DOI) | HTML |
Formula | C55 H47 P3 Pt Si |
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Calculated formula | C55 H46 P3 Pt Si |
SMILES | [Pt]12([P](c3ccccc3)(c3ccccc3)c3ccccc3)[P](c3ccccc3)(c3ccccc3)c3ccccc3[Si]1(C)c1ccccc1[P]2(c1ccccc1)c1ccccc1 |
Title of publication | Reaction of bis(o-phosphinophenyl)silane with M(PPh(3))(4) (M = Ni, Pd, Pt): synthesis and structural analysis of η(2)-(Si-H) metal(0) and pentacoordinate silyl metal(ii) hydride complexes of the Ni triad bearing a PSiP-pincer ligand. |
Authors of publication | Takaya, Jun; Iwasawa, Nobuharu |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2011 |
Journal volume | 40 |
Journal issue | 35 |
Pages of publication | 8814 - 8821 |
a | 19.567 ± 0.003 Å |
b | 12.9268 ± 0.0014 Å |
c | 19.692 ± 0.003 Å |
α | 90° |
β | 116.36 ± 0.02° |
γ | 90° |
Cell volume | 4463 ± 1.3 Å3 |
Cell temperature | 123 ± 2 K |
Ambient diffraction temperature | 123 ± 2 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/a 1 |
Hall space group symbol | -P 2yab |
Residual factor for all reflections | 0.1068 |
Residual factor for significantly intense reflections | 0.0832 |
Weighted residual factors for significantly intense reflections | 0.2017 |
Weighted residual factors for all reflections included in the refinement | 0.2223 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.065 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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