Information card for entry 7018906

Structure parameters

• Chemical name: bis((μ2-3,5-bis(trifluoromethyl)pyrazolato)-bis(η2-ethylene)-rhodium(i))
• Formula: C18 H18 F12 N4 Rh2
• Calculated formula: C18 H18 F12 N4 Rh2
• SMILES: [Rh]123(n4[n]([Rh]56([n]7n1c(C(F)(F)F)cc7C(F)(F)F)([CH2]=[CH2]5)[CH2]=[CH2]6)c(cc4C(F)(F)F)C(F)(F)F)([CH2]=[CH2]2)[CH2]=[CH2]3
• Title of publication: Rhodium pyrazolate complexes as potential CVD precursors.
• Authors of publication: Rivers, Joseph H.; Depue Anderson, Lauren J.; Starr, Cotton M. N.; Jones, Richard A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 17
• Pages of publication: 5401 - 5408
• a: 9.3215 ± 0.0017 Å
• b: 19.009 ± 0.003 Å
• c: 13.182 ± 0.002 Å
• α: 90°
• β: 101.582 ± 0.005°
• γ: 90°
• Cell volume: 2288.2 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0746
• Residual factor for significantly intense reflections: 0.0487
• Weighted residual factors for significantly intense reflections: 0.0915
• Weighted residual factors for all reflections included in the refinement: 0.1002
• Goodness-of-fit parameter for all reflections included in the refinement: 1.086
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No