Information card for entry 7018907

Structure parameters

• Chemical name: (μ2-3,5-bis(trifluoromethyl)pyrazolato)-(μ2-chloro)-tetra(trimethylphosphine)-dirhodiumrhodium(i)
• Formula: C17 H37 Cl F6 N2 P4 Rh2
• Calculated formula: C17 H37 Cl F6 N2 P4 Rh2
• SMILES: [Rh]1([Cl][Rh]([P](C)(C)C)([P](C)(C)C)[n]2n1c(C(F)(F)F)cc2C(F)(F)F)([P](C)(C)C)[P](C)(C)C
• Title of publication: Rhodium pyrazolate complexes as potential CVD precursors.
• Authors of publication: Rivers, Joseph H.; Depue Anderson, Lauren J.; Starr, Cotton M. N.; Jones, Richard A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 17
• Pages of publication: 5401 - 5408
• a: 13.489 ± 0.003 Å
• b: 10.512 ± 0.002 Å
• c: 21.222 ± 0.004 Å
• α: 90°
• β: 104.98 ± 0.03°
• γ: 90°
• Cell volume: 2906.9 ± 1.1 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0543
• Residual factor for significantly intense reflections: 0.0364
• Weighted residual factors for significantly intense reflections: 0.0751
• Weighted residual factors for all reflections included in the refinement: 0.0817
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No