Information card for entry 7024623

Structure parameters

• Formula: C175 H250 B F24 P6 Rh6
• Calculated formula: C175 H250 B F24 P6 Rh6
• Title of publication: Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).
• Authors of publication: Hiney, Rachel M.; Chaplin, Adrian B.; Harmer, Jeffrey; Green, Jennifer C.; Weller, Andrew S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 7
• Pages of publication: 1726 - 1733
• a: 17.4956 ± 0.0001 Å
• b: 20.5413 ± 0.0002 Å
• c: 24.3992 ± 0.0002 Å
• α: 89.4455 ± 0.0003°
• β: 88.7491 ± 0.0003°
• γ: 88.3928 ± 0.0003°
• Cell volume: 8762.74 ± 0.12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0816
• Residual factor for significantly intense reflections: 0.0503
• Weighted residual factors for significantly intense reflections: 0.1115
• Weighted residual factors for all reflections included in the refinement: 0.1263
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No