Information card for entry 7024866

Structure parameters

• Formula: C18 H26 N O6 P Si2 W
• Calculated formula: C18 H26 N O6 P Si2 W
• SMILES: C1(c2ccco2)N(C)[P]1(C([Si](C)(C)C)[Si](C)(C)C)[W](C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Novel access to azaphosphiridine complexes and first applications using Brønsted acid-induced ring expansion reactions.
• Authors of publication: Fankel, Stefan; Helten, Holger; von Frantzius, Gerd; Schnakenburg, Gregor; Daniels, Jörg; Chu, Victoria; Müller, Christina; Streubel, Rainer
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 14
• Pages of publication: 3472 - 3481
• a: 9.2166 ± 0.0003 Å
• b: 9.7609 ± 0.0005 Å
• c: 15.0733 ± 0.0004 Å
• α: 73.292 ± 0.002°
• β: 74.587 ± 0.002°
• γ: 78.755 ± 0.002°
• Cell volume: 1241.7 ± 0.08 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0367
• Residual factor for significantly intense reflections: 0.0315
• Weighted residual factors for significantly intense reflections: 0.0645
• Weighted residual factors for all reflections included in the refinement: 0.0661
• Goodness-of-fit parameter for all reflections included in the refinement: 0.997
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No