Information card for entry 7027080

Structure parameters

• Chemical name: tris(pentachlorophenyl)-rhodium(III) dichloromethane solvate
• Formula: C18.5 H Cl16 Rh
• Calculated formula: C18.501 Cl16.002 Rh
• Title of publication: Synthesis of the homoleptic rhodium(III) complex [Rh(C6Cl5)3]. Molecular structures of [Rh(C6Cl5)3] and [Rh(C6Cl4‒C6Cl4)(C6Cl5)(SC4H8)2]
• Authors of publication: García, María P.; Jiménez, M. Victoria; Lahoz, Fernando J.; López, José A.; Oro, Luis A.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 24
• Pages of publication: 4211
• a: 10.8207 ± 0.0011 Å
• b: 10.8539 ± 0.0015 Å
• c: 14.0152 ± 0.0015 Å
• α: 108.608 ± 0.005°
• β: 102.214 ± 0.004°
• γ: 106.976 ± 0.006°
• Cell volume: 1405.2 ± 0.3 ų
• Cell temperature: 233 ± 2 K
• Ambient diffraction temperature: 233 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0602
• Residual factor for significantly intense reflections: 0.0472
• Weighted residual factors for significantly intense reflections: 0.1215
• Weighted residual factors for all reflections included in the refinement: 0.1306
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No