Information card for entry 7027081

Structure parameters

• Chemical name: (octachloro-2,2'-biphenylene)-(pentachlorophenyl)- bis(tetrahidrothiophene)-rhodium(III)
• Formula: C26 H16 Cl13 Rh S2
• Calculated formula: C26 H8 Cl13 Rh S2
• Title of publication: Synthesis of the homoleptic rhodium(III) complex [Rh(C6Cl5)3]. Molecular structures of [Rh(C6Cl5)3] and [Rh(C6Cl4‒C6Cl4)(C6Cl5)(SC4H8)2]
• Authors of publication: García, María P.; Jiménez, M. Victoria; Lahoz, Fernando J.; López, José A.; Oro, Luis A.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 24
• Pages of publication: 4211
• a: 9.2192 ± 0.0005 Å
• b: 32.66 ± 0.002 Å
• c: 11.3747 ± 0.0007 Å
• α: 90°
• β: 105.805 ± 0.006°
• γ: 90°
• Cell volume: 3295.4 ± 0.4 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0539
• Residual factor for significantly intense reflections: 0.0364
• Weighted residual factors for significantly intense reflections: 0.0814
• Weighted residual factors for all reflections included in the refinement: 0.0913
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No