Information card for entry 7027158

Structure parameters

• Formula: C39 H33 Cl I O11 P3 W4
• Calculated formula: C39.5 H40 Cl I O11 P3 W4
• Title of publication: Cationic linear triphos, L [PhP(CH2CH2PPh2)2], alkyne complexes of molybdenum(II) and tungsten(II); crystal structures of [WI(CO)(L-P,P′,P ″)(η2-MeC2Me)]2[W6O19], [WI(CO)(L-P,P ′,P ″)(η2-MeC2Me)][BPh4] and [MoBr2(O){Ph2P(CH2)2PPh(CH2)2POPh2-P,P ′,O}]
• Authors of publication: Baker, Paul K.; Drew, Michael G. B.; Meehan, Margaret M.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 5
• Pages of publication: 765
• a: 11.759 ± 0.014 Å
• b: 14.428 ± 0.016 Å
• c: 14.855 ± 0.016 Å
• α: 78.131 ± 0.01°
• β: 88.426 ± 0.01°
• γ: 86.037 ± 0.01°
• Cell volume: 2460 ± 5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1637
• Residual factor for significantly intense reflections: 0.0941
• Weighted residual factors for significantly intense reflections: 0.2219
• Weighted residual factors for all reflections included in the refinement: 0.2638
• Goodness-of-fit parameter for all reflections included in the refinement: 1.3
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No