Information card for entry 7027306

Structure parameters

• Formula: C22 H47 N3 Na P Si2
• Calculated formula: C22 H47 N3 Na P Si2
• SMILES: [Na]12(P(C([Si](C)(C)C)[Si](C)(C)C)c3c(cccc3)C[N]1(C)C)[N](C)(C)CC[N]2(C)C
• Title of publication: Monomeric alkali metal complexes of a sterically demanding, donor-functionalised secondary phosphide ligand
• Authors of publication: Clegg, William; Doherty, Simon; Izod, Keith; Kagerer, Hartmut; O’Shaughnessy, Paul; Sheffield, Joanne M.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 11
• Pages of publication: 1825
• a: 9.5849 ± 0.0015 Å
• b: 11.8767 ± 0.0018 Å
• c: 14.424 ± 0.002 Å
• α: 67.669 ± 0.004°
• β: 87.913 ± 0.004°
• γ: 71.329 ± 0.003°
• Cell volume: 1432.1 ± 0.4 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0685
• Residual factor for significantly intense reflections: 0.0439
• Weighted residual factors for significantly intense reflections: 0.1057
• Weighted residual factors for all reflections included in the refinement: 0.1164
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No